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The specificity and structure of DNA crosslinking by the gut bacterial genotoxin colibactin
bioRxiv
The Role of the Unusual 2-Tyr-1-carboxylate Non-heme Iron Motif in the Mechanism of N,N-Dimethylformamidase
ChemRxiv
Excitonic anisotropy in single-crystalline 2D silver phenylchalcogenides
Regularized second order Møller-Plesset theory: Linear scaling implementation and assessment on large-molecule problems
Systematic Bandgap Engineering of a 2D Organic-Inorganic Chalcogenide Semiconductor via Ligand Modification
Role of Active Site Residues and Weak Noncovalent Interactions In Substrate Positioning in N,N-Dimethylformamidase
N,N-Dimethylformamide (DMF) is a pollutant that can be metabolized naturally by DMF-utilizing microorganisms, via the non-heme iron …
ChemRxiv
CH-π Interactions Confer Orientational Flexibility in Protein–Carbohydrate Binding Sites
Protein-carbohydrate binding is essential for biological function and is driven by non-covalent interactions, including hydrogen bonds …
ChemRxiv
Monocyclic Azetidines via a Visible-Light-Mediated Aza Paternò-Büchi Reaction of Ketone-Derived Sulfonylimines
Tracing the stepwise Darwinian evolution of a plant halogenase
Halogenation chemistry is rare in plant metabolism, with the chloroalkaloid acutumine produced by Menispermaceae species being the only …
bioRXiv
Controlled Gel Toughening with Tetrafunctional Cyclobutane Mechanophores
ChemRxiv