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Visible light–mediated aza Paternò–Büchi reaction of acyclic oximes and alkenes to azetidines
The aza Paternò–Büchi reaction is a [2+2]-cycloaddition reaction between imines and alkenes that produces azetidines, four-membered …
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Visible light–mediated aza Paternò–Büchi reaction of acyclic oximes and alkenes to azetidines
The tension-activated carbon–carbon bond
Mechanical force drives distinct chemical reactions; yet, its vectoral nature results in complicated coupling with reaction …
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The tension-activated carbon–carbon bond
Heterocyclic Modification Leading to Luminescent 0D Metal Organochalcogenide with Stable X-ray Scintillating Properties
Metal organochalcogenides (MOCs) are an emerging class of luminescent hybrid organic–inorganic semiconductors, whose structures and …
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Heterocyclic Modification Leading to Luminescent 0D Metal Organochalcogenide with Stable X-ray Scintillating Properties
Internal Catalysis in Dynamic Hydrogels with Associative Thioester Cross-links
Thioesters are an essential functional group in biosynthetic pathways, which has motivated their development as reactive handles in …
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Internal Catalysis in Dynamic Hydrogels with Associative Thioester Cross-links
Nested Non-covalent Interactions Expand the Functions of Supramolecular Polymer Networks
Supramolecular polymer networks contain non-covalent cross-links that enable access to broadly tunable mechanical properties and …
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Nested Non-covalent Interactions Expand the Functions of Supramolecular Polymer Networks
A semi-automated, high-throughput approach for the synthesis and identification of highly photo-cytotoxic iridium complexes
The discovery of new compounds with pharmacological properties is usually a lengthy, laborious and expensive process. Thus, there is …
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A semi-automated, high-throughput approach for the synthesis and identification of highly photo-cytotoxic iridium complexes
A Thermally Stable SO₂ Releasing Mechanophore: Facile Activation, Single-Event Spectroscopy, and Molecular Dynamic Simulations
Polymers that release small molecules in response to mechanical force are promising candidates as next-generation on-demand delivery …
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A Thermally Stable SO₂ Releasing Mechanophore: Facile Activation, Single-Event Spectroscopy, and Molecular Dynamic Simulations
Improving Gas Adsorption Modeling for MOFs by Local Calibration of Hubbard U Parameters
While computational screening with density functional theory (DFT) is frequently employed for the screening of metal-organic frameworks …
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Improving Gas Adsorption Modeling for MOFs by Local Calibration of Hubbard U Parameters
Self-Amplified HF Release and Polymer Deconstruction Cascades Triggered by Mechanical Force
Hydrogen fluoride (HF) is a versatile reagent for material transformation, with applications in self-immolative polymers, remodeled …
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Self-Amplified HF Release and Polymer Deconstruction Cascades Triggered by Mechanical Force
Angle-strained sila-cycloalkynes
Second row elements in small- and medium-rings modulate strain. Herein we report the synthesis of two novel oligosilyl-containing …
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Angle-strained sila-cycloalkynes